Universal rate constants for reactive collisions of ultracold molecules.

نویسندگان

  • Zbigniew Idziaszek
  • Paul S Julienne
چکیده

A simple quantum-defect model gives analytic expressions for the complex scattering length and threshold collision rates of ultracold molecules. If the probability of reaction in the short-range part of the collision is high, the model gives universal rate constants for s- and p-wave collisions that are independent of short-range dynamics. This model explains the magnitudes of the recently measured rate constants for collisions of two ultracold 40K87Rb molecules, or an ultracold 40K atom with the 40K87Rb molecule [S. Ospelkaus et al., Science 327, 853 (2010).

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Universal ultracold collision rates for polar molecules of two alkali-metal atoms.

Universal collision rate constants are calculated for ultracold collisions of two like bosonic or fermionic heteronuclear alkali-metal dimers involving the species Li, Na, K, Rb, or Cs. Universal collisions are those for which the short range probability of a reactive or quenching collision is unity such that a collision removes a pair of molecules from the sample. In this case, the collision r...

متن کامل

Collisional dynamics of ultracold OH molecules in an electrostatic field

Ultracold collisions of polar OH molecules are considered in the presence of an electrostatic field. The field exerts a strong influence on both elastic and state-changing inelastic collision rate constants, leading to clear experimental signatures that should help disentangle the theory of cold molecule collisions. Based on the collision rates, we discuss the prospects for evaporative cooling ...

متن کامل

Inelastic collisions of ultracold triplet Rb2 molecules in the rovibrational ground state

Exploring and controlling inelastic and reactive collisions on the quantum level is a main goal of the developing field of ultracold chemistry. For this, the preparation of precisely defined initial atomic and molecular states in tailored environments is necessary. Here we present experimental studies of inelastic collisions of metastable ultracold Rb2 molecules in an array of quasi-1D potentia...

متن کامل

Universalities in ultracold reactions of alkali-metal polar molecules

We consider ultracold collisions of ground-state heteronuclear alkali-metal dimers that are susceptible to four-center chemical reactions 2AB → A2 + B2 even at submicrokelvin temperatures. These reactions depend strongly on species, temperature, electric field, and confinement in an optical lattice. We calculate ab initio van der Waals coefficients for these interactions and use a quantum forma...

متن کامل

Inelastic collisions of ultracold polar molecules

The collisional stability of ultracold polar molecules in electrostatic traps is considered. Rate constants for collisions that drive molecules from weak-electric-field-seeking to strong-field-seeking states are estimated using a simple model that emphasizes long-range dipolar forces. The rate constants for collisional losses are found to vary substantially as a function of molecular parameters...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Physical review letters

دوره 104 11  شماره 

صفحات  -

تاریخ انتشار 2010